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Growth and magnetic properties of oriented α-Fe2O3 nanorods

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JOURNAL OF PHYSICAL CHEMISTRY B
卷 110, 期 37, 页码 18108-18111

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AMER CHEMICAL SOC
DOI: 10.1021/jp0644661

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alpha-Fe2O3 nanorods have been deposited on Si substrates using the metal-organic chemical vapor deposition method. Structural analyses indicated that alpha-Fe2O3 nanorods are preferentially oriented in the [104] direction on Si(100) substrates, and the nanorod possesses the single-crystalline structure. MFM image suggests that a spin domain is formed in the alpha-Fe2O3 nanorod. Anisotropic magnetic property of the alpha-Fe2O3 nanorods, i.e., the discrepancy of the saturation magnetization, is observed from SQUID measurements when the magnetic field are applied parallel and perpendicular to the substrate. A lower Morin temperature than that of the macroscopically crystalline hematite is observed when the magnetic field is applied parallel to the substrate.

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