期刊
JOURNAL OF POWER SOURCES
卷 159, 期 2, 页码 1158-1161出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.jpowsour.2005.12.015
关键词
solid oxide fuel cell; filter-coating; thin electrolyte film; yttria-stabilized zirconia
A simple and cost-effective technique, filter-coating, has been developed to fabricate dense electrolyte membranes. Eight mole percent yttria-stabilized zirconia (YSZ) electrolyte membrane as thin as 7 mu m was prepared by filter-coating on a porous substrate. The thickness of the YSZ film was uniform, and could be readily controlled by the concentration of the YSZ suspension and the rate of the suspension deposition. The YSZ electrolyte film was dense and was well bonded to the Ni-YSZ anode substrate. An anode-supported solid oxide fuel cell (SOFC) with a YSZ electrolyte film and a La0.85Sr0.15MnO3 (LSM) + YSZ cathode was fabricated and its performance was evaluated between 700 and 850 degrees C with humidified hydrogen as the fuel and ambient air as the oxidant. An open circuit voltage (OCV) of 1.09 V was observed at 800 degrees C, which was close to the theoretical value, and the maximum power density measured was 1050 mW cm(-1). The results demonstrate that the dense YSZ film fabricated by filter-coating is suitable for application to SOFCs. (c) 2006 Elsevier B.V. All rights reserved.
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