期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 12, 期 28, 页码 7304-7312出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.200600312
关键词
chirality; helical structures; oligothiophenes; self-assembly; thin films
A new class of chiral oligothiophenes is described. Mono-, bi-, ter-, and quarterthiophenes have been linked to enantiopure trans- 1,2-cyclohexanediamine (DACH) via diamino or diimino moieties. The stereochemistry of DACH, the type of linker, and oligothiophene size determine the conformational flexibility of these molecules and consequently their molecular and supramolecular helicity in solution and in the solid state. The case of diaminobis(bithiophene), which inverts helicity and shows chiral amplification in the transition from solution to film, is described in detail. Based on the combined use of circular dichroism in solution and in the solid state, single-crystal/thin-film X-ray diffraction, and polarized optical microscopy, a working mechanism has been proposed to explain this unexpected behavior.
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