期刊
ORGANIC LETTERS
卷 8, 期 20, 页码 4441-4443出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol061579u
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资金
- NIGMS NIH HHS [R01 GM057014, GM 57014, R01 GM057014-02] Funding Source: Medline
The catalytic, diastereoselective coupling of alpha-silyloxy aldehydes and alkynylsilanes catalyzed by a nickel(0) N-heterocyclic carbene complex provides an effective entry to anti-1,2-diols. The scope of couplings and extent of diastereoselection are excellent across a range of substrates.
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