Prevention of zinc corrosion in oxygenated 0.5 M NaCl by treatment in a cerium(III) nitrate solution and modification with sodium hexadecanoate

A self-assembled monolayer (SAM) of hexadecanoate ion C15H31CO2 (C(16)A-) was prepared on a zinc electrode covered with a layer of hydrated cerium(Ill) oxide Ce2O3. The protection of zinc against corrosion was examined for the electrode coated with the Ce2O3 layer and the C(16)A-SAM in an oxygenated 0.5 M NaCl solution. A more positive open-circuit potential of the coated electrode was maintained during immersion in the solution for 4 h than that of the uncoated one and polarization curves showed marked suppression of the anodic process, implying that the layer modified with the SAM acted as a passive film. The protective efficiency of the modified layer was extremely high, more than 99%. The zinc surface coated with the Ce2O3 layer and the C(16)ASAM was characterized by X-ray photoelectron and FTIR reflection spectroscopies and contact angle measurement with a drop of water. (c) 2006 Elsevier Ltd. All rights reserved.