期刊
CHEMICAL & PHARMACEUTICAL BULLETIN
卷 54, 期 10, 页码 1391-1396出版社
PHARMACEUTICAL SOC JAPAN
DOI: 10.1248/cpb.54.1391
关键词
electro-organic reaction; ortho-dihydroxybenzene; quasi-reversible process; (EC) mechanism; 2-phenyl-1,3-indandione
This is an environmentally friendly method in the field of electroorganic reactions under controlled potential electrolysis, without toxic reagents at a carbon electrode in an undivided cell which involves the (EC) Mechanism reaction and comprises two steps alternatively; (i) electrochemical oxidation and (ii) chemical reaction. In particular, the electrochemical oxidation of 4-tert-butylcatechol, 4-methylcatechol and 2,3-dihydroxybenzoic acid in the presence of 2-phenyl-1,3-indandione has been studied in a water-acetonitrile (90 : 10) mixture. The research includes the use of a variety of experimental techniques, such as cyclic voltammetry, controlled-potential electrolysis, and spectroscopic identification of products (FT-IR, H-1-NMR, and MS spectrometry).
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