期刊
JOURNAL OF SOL-GEL SCIENCE AND TECHNOLOGY
卷 40, 期 1, 页码 39-44出版社
SPRINGER
DOI: 10.1007/s10971-006-9150-8
关键词
sol-gel films; hybrid materials; diazo dye; dielectric relaxation spectroscopy; photochromic materials
Photochromic silica based organic-inorganic hybrid materials containing covalently linked cyanoazobenzene chromophores were investigated by optical and dielectric spectroscopy. These materials, obtained via sol-gel process, were deposited onto glass substrates by spin coating technique to achieve thin transparent films. To investigate photoinduced alignment, the UV-Vis absorption spectra of the sol-gel films were recorded under illumination with linearly polarized blue light. Dielectric relaxation spectroscopy revealed a variety of relaxation processes: the alpha-process related to the dynamic glass transition temperature located around 150 degrees C, and an Arrhenius-type beta-relaxation (activation energy 58-60 kJ/mol) that was assigned to orientational fluctuations involving the azobenzene group. The correspondence between dielectric and photochemical behavior was discussed.
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