期刊
ADVANCED SYNTHESIS & CATALYSIS
卷 348, 期 15, 页码 2063-2067出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.200600236
关键词
amination; diarylmethylamine; gold; indium; Lewis acid
The Lewis acid-mediated direct amination of benzylic alcohols is described, providing various benzylic amine derivatives in good yields under mild and environmentally benign conditions. Among the different Lewis acids tested, gold(III) proved to be the catalyst of choice for both chemical (yield, conversion) and practical reasons (a filtration over a silica pad is generally sufficient to obtain the corresponding benzylic amine in analytically pure form).
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