Lithium isotopic systematics of granites and pegmatites from the Black Hills, South Dakota

To study Li isotopic fractionation during granite differentiation and late-stage pegmatite evolution, Li isotopic compositions and concentrations have been measured for the S-type Harney Peak Granite, the spatially associated Tin Mountain pegmatite, and possible metasedimentary source rocks in the Black Hills, South Dakota. The Harney Peak Granite is isotopically heterogeneous, with 87 Li varying from -3.1 to +6.6. The delta(7) Li values of Proterozoic metasedimentary rocks that are possible sources of the Harney Peak Granite range from -3.1 to +2.5 and overlap with post-Archean shales and the Harney Peak Granite. For the granite suite, there is no correlation between delta Li-7 and elements indicative of degrees of granite differentiation (SiO2, Li, Rb, etc.). The Li isotopic composition of the Harney Peak Granite, therefore, appears to reflect the source composition. Minerals from the zoned Tin Mountain pegmatite have extremely high Li contents and heavier Li isotopic compositions than the granite or surrounding Black Hills metasedimentary rocks. The heavier compositions may reflect Li isotopic fractionation resulting from extensive crystal-melt fractionation. Lithium concentrations decrease in the order: spodumene (similar to 3.7 wt%), muscovite (0.2 to 2.0 wt%), plagioclase (100-1100 ppm), quartz (30-140 ppm). Plagioclase, muscovite, and spodumene in all zones display a relatively narrow range in 67 Li of +7.9 to +11.4. In contrast, quartz is isotopically heavier and more variable (+14.7 to +21.3), with delta Li-7 showing an inverse correlation with Li concentration. This correlation reflects the mixing of isotopically heavy Li in quartz and lighter Li in fluid inclusions, as documented by fluid inclusion compositions (delta Li-7 = +8.1 to +13.4 and Li of 280 to 3960 ppm). Extrapolation of this trend to an estimated intrinsic Li concentration in quartz of < 30 ppm, yields an inferred delta Li-7 for fluid inclusion-free quartz of >+21. The large difference in delta Li-7 between quartz and other minerals may reflect Li-7 preference for less highly coordinated sites, which have higher bond-energies (i.e., the two- or fourfold site in quartz vs. higher coordination number sites in other minerals). Comparison of the Li isotopic composition of fluid inclusions with that of the wall zone of the Tin Mountain pegmatite suggests similar to 4 parts per thousand isotopic fractionation during fluid exsolution, which agrees with the results derived from studies of hydrothermal alteration of basalts.