期刊
PHARMACEUTICAL BIOLOGY
卷 44, 期 7, 页码 528-533出版社
TAYLOR & FRANCIS INC
DOI: 10.1080/13880200600883064
关键词
coumarin; furocoumarin; pyranocoumarin; Seseli resinosum Freyn et Sint.; Umbelliferae
Seseli resinosum Freyn et Sint. (Umbelliferae) is a perennial herb that grows in the northern region of Anatolia, Turkey. The n-hexane extract obtained from the roots of S. resinosum was investigated for the presence of coumarins. Three angular-type pyranocoumarins and two linear-type furo-coumarins were isolated from the roots. The compounds were identified as (+)-samidin [(3'S, 4'S)-3'-senecioyloxy-4'-acetoxy-3', 4'-dihydroseselin] (1), (-)- anomalin [(3'R, 4'R)-3', 4'-diangeloyloxy-3', 4'-dihydroseselin] (2), calipteryxin (3'R, 4'R)- 3'- angeloyloxy- 4'- senecioyloxy- 3', 4'-dihydroseselin (3), isoimperatorin (4), and deltoin (5). The structures were determined using spectroscopic methods (H-1 NMR, C-13 NMR, H-1-H-1 COSY, H-1-C-13 COSY, HMBC, MS), physical methods (melting point and optical rotation), and chemical correlations with known compounds that have been described in the literature. The chemotaxonomic significance of these isolated coumarins is discussed in the genus Seseli L.
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