期刊
EUROPEAN POLYMER JOURNAL
卷 42, 期 10, 页码 2532-2539出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.eurpolymj.2006.04.014
关键词
chiral separation; membrane; molecular imprinting; myrtenal; optical resolution; polysulfone; perm selectivity; adsorption selectivity; diffusivity selectivity
Novel polymeric materials, having a chiral environment, were obtained by the reaction of lithiated polysulfone with chiral terpenoid myrtenal. The resulting polymers gave self-standing durable membranes. Molecularly imprinted membranes were prepared from the novel myrtenal-containing polysulfones by the presence of print molecules during the membrane preparation process. The D-isomer imprinted membrane showed D-isomer adsorption and diffusivity selectivity, and vice versa. As a result, the D-isomer imprinted membrane transported the D-isomer in preference to the L-isomer, and vice versa. The control non-imprinted membrane also showed permselectivity toward racemic glutamic acid mixtures. The expression of permselectivity for the molecularly imprinted membranes was synergistically due to adsorption and diffusivity selectivity. (c) 2006 Elsevier Ltd. All rights reserved.
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