The structure and physical properties of polypropylene and thermoplastic olefin nanocomposites containing nanosilica

The morphology and physical properties of thermoplastic olefin blend (TPO) based nanocomposites containing nanosilica are reported. Addition of maleated PP resulted in improved filler dispersion within the PP matrix, where the filler resided exclusively. This separated morphology resulted in selective reinforcement of the PP matrix without compromising ductility, as demonstrated by mechanical property characterization. The tensile moduli, impact and flexural properties of TPO/nanosilica composites showed improvements at low loadings of nanosilica, indicating a good balance of stiffness and toughness. The addition of nanosilica into the TPOs decreased the size of the dispersed elastomer phase, which was a factor in the observed improvements of impact strength. Silane-modified nanosilica dispersed more efficiently in the polymer matrix, giving rise to improved impact properties of the TPO composites, compared to the unmodified filler. (c) 2006 Elsevier Ltd. All rights reserved.