期刊
MACROMOLECULAR MATERIALS AND ENGINEERING
卷 291, 期 10, 页码 1287-1292出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/mame.200600216
关键词
cationic UV curing; hybrid nanocoatings; hyperbranched polymers; sol-gel process
Organic-inorganic nanocomposite hybrid coatings were prepared through a dual-cure process involving cationic photopolymerization of a hyperbranched epoxy functionalized resin and subsequent condensation of an alkoxysilane inorganic precursor. All the formulations investigated gave rise to photocured films characterized by high gel content values. An increase in glass transition temperature and an increase in storage modulus above T-g in the rubbery plateau is observed with increasing TEOS content in the photocurable formulation. The important role of GPTS on reducing the inorganic domain size and avoiding macroscopic phase separation was demonstrated by TEM analyses.
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