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Simultaneous ejection of six electrons at a constant potential by hexakis(4-ferrocenylphenyl) benzene

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卷 8, 期 22, 页码 5041-5044

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AMER CHEMICAL SOC
DOI: 10.1021/ol061904d

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A simple synthesis of a dendritic hexaferrocenyl electron donor (5) is described in which six ferrocene moieties are connected at the vertices of the propeller of the hexaphenylbenzene core. The molecular structure of 5 is confirmed by X-ray crystallography. An electrochemical analysis along with redox titrations (which are tantamount to coulometry) confirmed that it ejects six electrons at a single potential.

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