期刊
JOURNAL OF POWER SOURCES
卷 161, 期 2, 页码 1319-1323出版社
ELSEVIER
DOI: 10.1016/j.jpowsour.2006.06.035
关键词
lithium-ion batteries; anode materials; Si composites; metal-organic compound
A carbon-coated Si-Cu3Si composite material is prepared using silicon and copper(II) D-gluconate powders by simple mechanical milling and pyrolysis, and is investigated as an anode material for lithium-ion batteries. In this process, the Cu3Si and pyrolyzed carbon uniformly adhere to the surface of the silicon particles. The cycling performance of the composite material exhibits a stable capacity of 850 mAh g(-1) for 30 cycles. The improved cycling performance is attributed to the fact that the copper silicide and pyrolyzed carbon provide both a better electrical contact with the current-collector and a buffering effect for the volume expansion-contraction during cycling. (c) 2006 Elsevier B.V. All rights reserved.
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