Semiclassical dynamics of electrons in magnetic Bloch bands:: A Hamiltonian approach

By formally diagonalizing with accuracy h the Hamiltonian of electrons in a crystal subject to electromagnetic perturbations, we resolve the debate on the Hamiltonian nature of semiclassical equations of motion with Berry-phase corrections, and therefore confirm the validity of the Liouville theorem. We show that both the position and momentum operators acquire a Berry-phase dependence, leading to a non-canonical Hamiltonian dynamics. The equations of motion turn out to be identical to the ones previously derived in the context of electron wave-packets dynamics.