期刊
RUSSIAN CHEMICAL BULLETIN
卷 55, 期 11, 页码 1869-1882出版社
SPRINGER
DOI: 10.1007/s11172-006-0528-0
关键词
1,3-dipolar cycloaddition; nitriles; nitrile complexes; nitrones; reactivity
Data on 1,3-dipolar cycloaddition of nitrones to free and coordinated nitriles producing 2,3-dihydro-1,2,4-oxadiazoles (or Delta(4)-1,2,4-oxadiazolines) are summarized. The latter compounds belong to the virtually unknown class of heterocyclic systems. The main factors responsible for the cycloaddition reactions are discussed. Particular attention is given to the role of metal centers in controlling the synthesis of 2,3-dihydro-1,2,4-oxadiazoles.
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