期刊
ADVANCED SYNTHESIS & CATALYSIS
卷 348, 期 16-17, 页码 2363-2370出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.200600351
关键词
asymmetric synthesis; Bronsted acid; cyclopropanes; Simmons-Smith reaction; TADDOL-phosphate
The synthesis of new chiral TADDOL-derived phosphate ligands is described. The ligands were efficiently synthesized on a multi-gram scale in three steps starting from the readily available corresponding TADDOL and were fully characterized. An X-ray structure was obtained and compared to known BINOL-phosphates. Their use in the asymmetric Simmons-Smith cyclopropanation of both functionalized and unfunctionalized olefins gave the desired cyclopropanes in good yields and good to moderate enantioselectivities.
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