期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 71, 期 23, 页码 8755-8760出版社
AMER CHEMICAL SOC
DOI: 10.1021/jo061442h
关键词
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Enantioenriched propargyl mesylates or perfluorobenzoates react with alpha-(N-carbamoyl)alkylcuprates to afford scalemic alpha-(N-carbamoyl) allenes which undergo N-Boc deprotection and AgNO3-promoted cyclization to afford N-alkyl-3-pyrrolines. The synthetic sequence proceeds under optimal conditions with no loss of enantiopurity relative to the starting propargyl alcohols prepared by asymmetric addition of terminal alkynes to aldehydes.
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