期刊
TETRAHEDRON
卷 62, 期 46, 页码 10753-10761出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2006.08.093
关键词
microemulsion; singlet oxygen; multiphase media; hydrogen peroxide
The disproportionation of hydrogen peroxide catalyzed by molybdate anions provides an effective non-photochemical source of singlet oxygen O-1(2), ((1)Delta(g)). Microemulsions are the preferred media to carry out 'dark' singlet oxygenation of labile and hydrophobic substrates. Single-phase and multiphase microemulsion systems have been developed and improved for the last decade and their respective advantages and limitations are shortly reviewed and discussed. (c) 2006 Elsevier Ltd. All rights reserved.
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