4.7 Article

Mechanism of physical transformations of mineral matter in the blast furnace coke with reference to its reactivity and strength

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ENERGY & FUELS
卷 20, 期 6, 页码 2632-2635

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AMER CHEMICAL SOC
DOI: 10.1021/ef060147x

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Examinations of polished and dry cut sections of feed and tuyere coke revealed some possible mechanisms for the physical influence of mineral compounds on the reactivity and strength of coke. It was observed that rounded particles of mineral phases that are exposed to the pore walls and surface of coke at high temperature create an inorganic cover, thus reducing the surface available for gas-solid reactions. The particles of mineral matter that have a low melting point and viscosity can affect the coke at earlier stages in the blast furnace process, acting in the upper parts of the blast furnace (BF). The temperature-driven redistribution of mineral phases within the coke matrix probably leads to the creation of weak spots and in general to anisotropy in its properties, thus reducing its strength.

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