4.8 Article

Novel tetramethoxy resorcinarene bis-crown ethers

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ORGANIC LETTERS
卷 8, 期 24, 页码 5473-5476

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AMER CHEMICAL SOC
DOI: 10.1021/ol062138d

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The synthesis and characterization of new tetramethoxy resorcinarene bis-crown ethers BC4 and BC5 are described. The complexation properties of the compounds toward alkali metal cations were studied by H-1 NMR spectroscopy and X-ray crystallography, which revealed that BC5 can accommodate two cations simultaneously inside the crown pockets formed by the crown ether bridges and the resorcinarene skeleton.

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