期刊
CARBOHYDRATE POLYMERS
卷 66, 期 4, 页码 537-545出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.carbpol.2006.04.023
关键词
biocomposite; biodegradable; lignocellulose fillers; lignin extraction; wheat straw
The paper is focused on the analysis of the behaviour of biocomposites (biodegradable composites) which are reinforced with different fillers fractions, with varying lignin contents. These materials have been carried-out by extrusion and injection moulding. The matrix, an aromatic copolyester (polybutylene adipate-co-terephthalate), is biodegradable. The lignocellulose fillers are a by-product of an industrial fractionation process of wheat straw. From the raw agro-material and by lignin extractions, various fillers fractions have been obtained by varying the fractionation conditions, both on the liquid media (aqueous or organic) and on the temperature. The fillers lignin contents vary from 30 to 14 wt% with a resultant increase of the cellulose content. We have analysed the impact of the different extraction conditions on the fillers surface and size distribution, and also on the final thermal and mechanical properties of the biocomposites. These materials present significant differences of behaviour which can fulfil some requirements for applications, such as non-food packaging or other short-lived applications (agriculture, sport...) where long-lasting polymers are not entirely adequate. (c) 2006 Elsevier Ltd. All rights reserved.
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