期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 71, 期 24, 页码 9248-9251出版社
AMER CHEMICAL SOC
DOI: 10.1021/jo061739f
关键词
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[GRAPHICS] A novel rhodium-catalyzed hydrophosphination of alkynes using a silylphosphine as a phosphino group source is described. A variety of alkynes, both terminal and internal ones with aryl, alkyl, and carboxyl groups, gave the corresponding alkenylphosphines in a highly regioselective and syn-selective manner. Alkenes with an electron-withdrawing group also gave the corresponding adducts in good yields.
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