期刊
TETRAHEDRON LETTERS
卷 47, 期 48, 页码 8463-8466出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2006.09.154
关键词
iodine; solvent-free; alcohols; catalyst
Iodine has been shown to be an efficient catalyst for transformations of alcohols under solvent-free conditions. In the presence of 5% of iodine, tertiary alcohols underwent dehydration forming the corresponding alkenes, while in the case of 2-phenylpropane-2-ol cyclodimerisation to 1,1,3-trimethyl-3-phenylindane took place. Secondary and primary benzyl alcohols under the same conditions gave the corresponding ethers. (c) 2006 Elsevier Ltd. All rights reserved.
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