期刊
COORDINATION CHEMISTRY REVIEWS
卷 250, 期 23-24, 页码 2929-2938出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.ccr.2006.09.001
关键词
anion; array; assay; calix[4]pyrrole; chromophore; colorimetric; confused; sensor
This is a first review devoted to N-confused calix[4]pyrroles (NCCPs). NCCPs are a relatively recent arrival to the family of the pyrrole-based anion binding macrocycles, being for the first time identified in 1999. Yet, in a relatively short time these calix[4]pyrrole (CP) isomers attracted attention of the community of research groups interested in anion binding and sensing. This is because they are relatively easy to synthesize, but mainly because they posses anion-binding properties that are different from that of regular calix[4]pyrroles. The difference in anion-binding properties stems from a different binding mode between the NCCP and anion. While the regular CPs adopt in the complex an ideal cone-like conformation where all four pyrroles-NHs engage in hydrogen bonding to the anion, the inverted pyrroles do not allow forming the cone. NCCPs bind anions via a confused cone (CC), by three NH hydrogen bonds with an anion and a CH-anion contact. This different binding mode results also in different anion-binding affinity and selectivity compared to regular CPs. Also, the inverted pyrroles offer a unique possibility for selective chemical modification of the receptor. The corresponding colorimetric sensors were tested for anion binding applications. The results of colorimetric assays for anions are presented and potential applications discussed. (c) 2006 Elsevier B.V. All rights reserved.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据