Levels and vertical distribution of PCBs in agricultural and natural soils from Sweden

Soils represent an important reservoir for persistent organic pollutants (POPs) in the terrestrial environment and thus the fate of contaminants deposited to the surface soils is important to understand. Since only a limited number of studies of the vertical distribution of POPs are available in the literature, the purpose of this study was to collect and analyze PCB concentrations in different layers of soil cores taken at agricultural and non-agricultural sites in Sweden. PCB concentrations at the agricultural site were nearly uniform on a dry weight basis throughout the depth considered (0-12 cm) while a distinct gradient with depth was observed at the five non-agricultural sites. On an organic carbon normalized basis, the concentration gradient was maintained at three of the non-agricultural sites while a more uniform distribution was observed at the other two sites. A statistically significant relationship between dry weight soil concentrations and organic carbon content was determined for all PCB congeners in the surface layers (0-1 cm) but not in the deeper layers (4-5 cm, 9-10 cm). These results were interpreted in relation to vertical soil transport processes and then the implications for environmental fate models including soil compartments were discussed. (c) 2006 Elsevier B.V. All rights reserved.