期刊
PHYSICS AND CHEMISTRY OF MINERALS
卷 33, 期 10, 页码 691-698出版社
SPRINGER
DOI: 10.1007/s00269-006-0118-6
关键词
elastic constants; composition; lattice parameters; fiber reinforced CMCs
The composition, lattice parameters, and elastic constants of natural single crystal YPO4 xeno-time from Novo Horizonte (Brazil) were determined using EPMA, XRD, and the pulse-echo technique. The composition indicates a 24% substitution of Y sites with other rare-earth elements. The lattice parameters of the studied crystal deviated only slightly from those reported for synthetic YPO4 and were in a good agreement with trends obeyed by other orthophosphates with the xenotime structure. The measured elastic constants C-11, C-33, C-44, and C-66 were consistent with synthetic crystals when porosity was accounted for. C-12 and C-13 constants were evaluated based on the comparison with other materials with xenotime structure. The elastic constants could be rationalized using interionic force constants and bond energies.
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