期刊
POLYMER DEGRADATION AND STABILITY
卷 91, 期 12, 页码 3371-3382出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.polymdegradstab.2006.05.012
关键词
ionic liquid; plasticizer; poly(vinyl chloride); leaching; high temperature stability; UV stability
Room temperature ionic liquids (ILs), based on ammonium, imidazolium and phosphonium cations, were studied as novel plasticizers for poly(vinyl chloride), PVC. All the ILs tested were able to produce flexible PVC. Upon 20 wt% plasticization, some of the ILs lowered the glass transition temperature (T-g) of PVC more than that done by several traditional plasticizers. They showed good thermodynamic compatibility as well. Several ILs showed better leaching and migration resistance than the traditional plasticizers. This was, in particular, a significant observation considering the ongoing controversy regarding the leaching and migration issues of the commonly-used phthalate plasticizers. High temperature and ultraviolet (UV) ray stability of IL-plasticized PVC samples were also studied. (c) 2006 Elsevier Ltd. All rights reserved.
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