期刊
JOURNAL OF SOLUTION CHEMISTRY
卷 35, 期 12, 页码 1621-1630出版社
SPRINGER/PLENUM PUBLISHERS
DOI: 10.1007/s10953-006-9087-0
关键词
thermoelectrochemical systems; Soret coefficients; thermal diffusion; HCl; water plus alcohol mixture
Standard entropies of the thermal diffusion transference of HCl, entropies of the moving H+ and Cl- ions, and Soret coefficients of this electrolyte at 298 K were obtained from a thermoelectrochemical investigation of HCl in water + alcohol solvent systems. The thermoelectric powers of the silver/silver chloride and para-benzoquinone/hydroquinone thermocells have been measured. Effects of the mixed solvent composition and the nature of an alcohol on the thermal diffusion characteristics were discussed using the theories of De Bethune and Agar.
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