期刊
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE
卷 62, 期 -, 页码 M3580-M3581出版社
BLACKWELL PUBLISHING
DOI: 10.1107/S1600536806050483
关键词
single-crystal X-ray study; T=298 K; mean sigma(N-C)=0.005 angstrom; R factor=0.045; wR factor=0.117; data-to-parameter ratio=13.2
In the centrosymmetric dinuclear title complex, [Cu-2(CH3O)(2)-(C4H8N3O2)(2)], the two Cu-II ions are linked by a pair of methoxide bridges, with a non-bonding Cu center dot center dot center dot Cu distance of 3.048 (1) angstrom. Each Cu-II center adopts a CuO2N2 square-planar geometry, coordinated by the bidentate bis(methoxycarbimido) aminate and two methoxide ligands.
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