期刊
TETRAHEDRON LETTERS
卷 47, 期 49, 页码 8661-8665出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2006.09.157
关键词
thiazoles; thia-Michael; benzotriazoles; desilylation
A mild and efficient method for the synthesis of substituted thiazoles is reported via one-pot N-desilylation, thioacylation/oxythioacylation/thiothioacylation followed by thia-Michael cycloisomerisation. This method has a general applicability to introduce various oxo and thio functionalities including aliphatic and aromatic moieties, especially at the C2-position of thiazoles. (c) 2006 Elsevier Ltd. All rights reserved.
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