期刊
TETRAHEDRON LETTERS
卷 47, 期 49, 页码 8737-8740出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2006.10.003
关键词
asymmetric allylic amination; asymmetric catalysis; diaminophosphine oxide; iridium
An Ir-catalyzed asymmetric allylic amination using chiral diaminophosphine oxide is described. Asymmetric allyno amination of terminal allylic carbonates proceeded in the presence of 2 mol % of Ir catalyst, 2 mol % of chiral diaminophosphine oxide, 5 mol % of NaPF6, and BSA, affording the chiral branched allylic amines in up to 95% cc. (c) 2006 Elsevier Ltd. All rights reserved.
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