期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 71, 期 25, 页码 9403-9410出版社
AMER CHEMICAL SOC
DOI: 10.1021/jo061749g
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资金
- EPSRC [EP/D075335/1] Funding Source: UKRI
- Engineering and Physical Sciences Research Council [GR/S50397/01, EP/D075335/1, GR/S50380/01] Funding Source: researchfish
N-H carbazoles can be produced from 2-chloroanilines and aryl bromides via consecutive catalytic amination and C-H activation. In many instances, this can be done in a tandem manner in one pot. The methodologies developed can be used in the synthesis of a range of carbazoles, including the natural products Clausine P and glycozolidine and a precursor in the synthesis of Clausines H, K, O, and 7-methoxy-O-methylmukonal, and can be extended to the synthesis of indoles.
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