期刊
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY
卷 44, 期 24, 页码 7014-7026出版社
WILEY
DOI: 10.1002/pola.21780
关键词
copolymerization; 4,4 '-dihydroxybenzophenone; divinylbenzene; 2,3-epoxy-propyl methacrylate; porous structure; surfaces
A new aromatic, tetrafunctional methacrylate monomer, 4,4'-di(2-hydroxy-3-methacryloyloxypropoxy)benzophenone, and its application to the synthesis of porous microspheres are presented. This new monomer was copolymerized with divinylbenzene in the presence of pore-forming diluents. The proper-ties of the obtained highly crosslinked microspheres were investigated as column packing for high-performance liquid chromatography. Their porous structures in both dry and wet states were studied and compared with those of poly(divinylbenzene) and the less crosslinked copolymer of 2,3-epoxypropyl methacrylate and divinylbenzene. (c) 2006 Wiley Periodicals, Inc.
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