期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 128, 期 50, 页码 16224-16230出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja065213o
关键词
-
资金
- NIGMS NIH HHS [R01 GM065255, R01 GM065255-04] Funding Source: Medline
It has been shown by us in a recent communication that homopolymers, in which each repeat unit contains a hydrophilic and a hydrophobic head group, are capable of forming environment-dependent micellar or inverse micellar assemblies. A systematic structure-property relationship study is carried out here to test the scope of the design. We show here that the molecular design is indeed broadly applicable and that there is a significant gain in the critical aggregation concentrations of these polymers, as compared to the small molecule counterparts. We also show that the design can be tuned to achieve vesicle-type assemblies, which further expands the repertoire of amphiphilic homopolymers in a variety of areas. Characterizations of these assemblies have been carried out using transmission electron microscopy, dynamic light scattering, static light scattering, and dye incorporation experiments.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据