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Interaction between charged colloids in a low dielectric constant solvent

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EPL
卷 78, 期 3, 页码 -

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EPL ASSOCIATION, EUROPEAN PHYSICAL SOCIETY
DOI: 10.1209/0295-5075/78/38002

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Based on computer simulations of the primitive model of electrolytes, we show that the effective interaction between low-charge colloids in solvents of low or moderate dielectric constant depends crucially on the salt concentration. While in the absence of salt the interaction is repulsive in agreement with Derjaguin-Landau-Verwey-Overbeek theory, depletion of salt Bjerrum pairs around the colloids leads to an attraction between like-charge colloids even at small salt concentrations. Copyright (C) EPLA, 2007.

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