4.7 Article

An efficient biomimetic Fe-catalyzed epoxidation of olefins using hydrogen peroxide

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CHEMICAL COMMUNICATIONS
卷 -, 期 3, 页码 289-291

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ROYAL SOC CHEMISTRY
DOI: 10.1039/b612048b

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A new, environmentally benign and practical epoxidation method was developed using inexpensive and efficient Fe catalysts. FeCl3 center dot 6H(2)O in combination with commercially available pyridine-2,6-dicarboxylic acid and amines showed excellent reactivity and selectivity towards aromatic olefins and moderate reactivity towards 1,3-cyclooctadiene utilizing H2O2 as the terminal oxidant.

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