4.7 Article

Organocatalytic asymmetric hydrophosphination of nitroalkenes

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CHEMICAL COMMUNICATIONS
卷 -, 期 7, 页码 722-724

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ROYAL SOC CHEMISTRY
DOI: 10.1039/b613477g

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The use of a bifunctional Cinchona alkaloid catalyst has provided a new organocatalytic strategy for the enantioselective addition of diphenylphosphine to a range of nitroalkenes, affording optically active beta-nitrophosphines (up to 99% ee after crystallization); this organocatalytic approach, providing a direct route to a new class of potentially useful enantiopure P,N-ligands, constitutes a bridge between the two complementary areas of asymmetric catalysis: organo- and metal-catalyzed transformations.

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