Effect of hot water immersion on the performance of carbon reinforced unidirectional poly(ether ether ketone) (PEEK) composites:: Stress rupture under end-loaded bending

This paper describes the behaviour of AS4 and T700SC reinforced PEEK composites (SUPreM (TM) and ACP-2) under applied compressive bending strain. The effect of an increased molecular weight of the polymer matrix on the residual time under endloaded compression bending conditions is studied. Generally for a given composite material, the higher the testing temperature and the applied strain the faster the failure occurs. At test temperatures exceeding the glass transition temperature or at high strain ratios the time-to-failure for CF/PEEK composites follows a master curve. The residual times under endloaded compression bending conditions increase with increasing toughness of the PEEK matrix but decrease with increasing tensile strength of the reinforcing fibres. It seems that the better the fibre/matrix adhesion the lower is the time to failure of an endloaded composite, because more load is transferred from the matrix into the fibres. In order to simulate composite applications under 'harsh' conditions the CF/PEEK composites have been exposed to boiling water. PEEK is known to be highly resistant to environmental effects, but water uptake significantly influences the overall performance of CF/ PEEK composites under endloaded compression bending conditions. The tensile properties of the composites have been measured as function of exposure time in boiling water. The fibre dominated uniaxial tensile strength is not/or only slightly affected by the boiling water conditioning even after extended exposure times but the transverse tensile strength decreases significantly after exposure to boiling water. The performance of SUPreM (TM) CF/PEEK-150 and 450 composites under endloaded compression bending conditions are positively affected by water conditioning whereas APC-2 fails at shorter residual times. The fracture behaviour under endloaded conditions is also affected by the ingress of water into the composite. The obtained results show clearly that applications of thermoplastic composites leading to large out of plane deformations can only be 'safe' if the maximum service temperatures of the finished part will be well below the glass transition temperature of the polymer matrix otherwise even at low bending radii a dramatic failure of the material cannot be excluded. (c) 2006 Elsevier Ltd. All rights reserved.