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Carbohydrates as synthetic tools in organic chemistry

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CHEMISTRY-A EUROPEAN JOURNAL
卷 13, 期 31, 页码 8649-8659

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WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.200701010

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carbohydrates; chiral auxiliary; chiral ligand; organocatalyst; stereoselective synthesis

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While amino acids, terpenes and alkaloids have found broad application as tools in stereoselective organic synthesis, carbohydrates have only lately been recognised as versatile starting materials for chiral auxiliaries, reagents, ligands and organocatalysts. The structural diversity of carbohydrates and the high density of functional groups offer a wide variety of opportunities for derivatization and tailoring of synthetic tools to a specific problem.

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