期刊
CHEMICAL SOCIETY REVIEWS
卷 36, 期 11, 页码 1803-1822出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/b605183a
关键词
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This critical review aims at presenting recent developments in intramolecular aromatic homolytic substitution which has become one of the common methodologies in modern synthesis. The application of Bu3SnH- mediated cyclisations have proved especially useful. The critical review illustrates the mechanistic considerations required for planning synthetic applications and a wide range of synthetic protocols and natural product syntheses are shown. The latest evidence for the mechanisms involved in aromatic homolytic substitution are presented. ( 152 references).
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