期刊
NEW JOURNAL OF CHEMISTRY
卷 31, 期 1, 页码 169-177出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/b609117b
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Complexation properties of pyrogallarene 1 towards small quaternary and tertiary alkyl ammonium cations were studied in gas phase, solution and in solid state. In gas phase both dimeric capsules and monomeric 1:1 complexes of all cations 2a(+)-d(+) are detected but only in the case of 2a(+) is the abundance of the capsule form higher than the monomeric 1:1 complex. A similar trend is observed in NMR experiments, which reveal a favourable dimeric complex for 2a(+) and a weaker dimeric complex for 2b(+) but only monomeric complexes for 2c(+) and 2d(+). Also in solid state, 2a(+) and 2b(+) form capsules when crystallized from MeOH while 2c(+) and 2d(+) form dimeric 1:1 complexes. As a reference, hetero-conformational dimeric capsule EtOH@1(2) obtained from the crystallization without any guest, is reported. The capsule consists of two directly hydrogen-bonded pyrogallarenes 1, one in boat conformation and the other in crown conformation, and encloses a molecule of ethanol.
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