期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 13, 期 2, 页码 436-449出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.200600889
关键词
charge carrier mobility; dyes/pigments; liquid crystals; perylene bisimide; self-assembly
The self-assembly of a new, highly fluorescent perylene bisimide dye 2 into a stacks, both in solution and condensed phase, has been studied in detail by NMR spectroscopy, vapor pressure osmometry (WO), UV/Vis and fluorescence spectroscopy, differential scanning calorimetry (DSC), optical polarizing microscopy (OPM) and X-ray diffraction. The NMR and VPO measurements revealed the formation of extended a-a stacks of the dye molecules in solution. The aggregate size determined from VPO and DOSY NMR measurements agree well with that obtained from the concentration and temperature-dependent UV/Vis spectral data by employing the isodesmic model (equal K model). In the condensed state, dye 2 possesses a hexagonal columnar liquid crystalline (LC) phase as confirmed by X-ray diffraction analysis. The columnar stacking of this dye has been further explored by atomic force microscopy (AFM). Well-resolved columnar nanostructures of the compound are observed on graphite surface. A color-tunable luminescence from green to red has been observed upon aggregation which is accompanied by an increase of the fluorescence lifetime and depolarization. The observed absorption properties can be explained in terms of molecular exciton theory. ne charge transport properties of dye 2 have been investigated by pulse radiolysis-time resolved microwave conductivity measurements and a ID charge carrier mobility up to 0.42 cm(2)V(-1)S(-1) is obtained. Considering the promising self-assembly, semi-conducting, and luminescence properties of this dye, it might serve as a useful functional material for nano-(opto)electronics.
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