Preparation and mechanical properties of modified epoxy resins with flexible diamines

Diglycidyl ether of bisphenol A (DGEBA) is one of the most widely used epoxy resins for many industrial applications, including cryogenic engineering. In this paper, diethyl toluene diamine (DETD) cured DGEBA epoxy resin has been modified by two flexible diamines (D-230 and D-400). The cryogenic mechanical behaviors of the modified epoxy resins are studied in terms of the tensile properties and Charpy impact strength at cryogenic temperature (77 K) and compared to their corresponding properties at room temperature (RT). The results show that the addition of flexible diamines generally improves the elongation at break and impact strength at both RT and 77 K. The exception is the impact strength at 77 K filled with 21 wt% and 49 wt% D-400. Further, two interesting observations are made: (a) the cryogenic tensile strength increases with increasing the flexible diamine content; and (b) the RT tensile strength can only be improved by adding a proper content of flexible diamines. It is concluded that the addition of a selected amount namely 21-78 wt% of D-230 can simultaneously strengthen and toughen DGEBA epoxy resins at both RT and 77 K. However, only the addition of 21 wt% D-400 can simultaneously enhance the strength and ductility/ impact strength of DGEBA epoxy resins at RT. The impact fracture surfaces are examined using scanning electron microscopy (SEM) to explain the impact strength results. Finally, differential scanning calorimetry (DSC) analysis shows that the glass transition temperature (T-g) decreases with increasing the flexible diamine content. The presence of a single T-g reveals that the flexible diamine-modified epoxy resins have a homogeneous phase structure. (c) 2006 Elsevier Ltd. All rights reserved.