Product pair correlation in bimolecular reactions

The vast majority of chemical reactions involve polyatomic species as reactants and/or products. The added degree of complexity offers opportunities to address dynamical questions other than those already encountered in a typical atom + diatom reaction. Product pair correlation is one of them. This article introduces the basic concept, outlines the experimental approach we developed and then highlights some of the applications to bimolecular reaction dynamics. Particular emphasis is placed on the information contents and unique insights gained from this type of measurements, which otherwise would have been lost by the conventional approach.