Nickel hydroxide/activated carbon composite electrodes for electrochemical capacitors

In this paper, a nickel hydroxide/activated carbon (AC) composite electrode for use in an electrochemical capacitor was prepared by a simple chemical precipitation method. The structure and morphology of nickel hydroxide/AC were characterized by X-ray diffraction (XRD) and scanning electron microscopy (SEM). The results showed that nano-sized nickel hydroxide was loading on the surface of activated carbon. Electrochemical performance of the composite electrodes with different loading amount was studied by cyclic voltammetry and galvanostatic charge/discharge measurements. It was demonstrated that the introduction of a small amount of nickel hydroxide to activated carbon could promote the specific capacitance of a composite electrode. The composite electrodes have good electrochemical performance and high charge-discharge properties. Moreover, when the loading amount of nickel hydroxide was 6 wt.%, the composite electrode showed a high specific capacitance of 314.5 F g(-1), which is 23.3% higher than pure activated carbon (255.1 Fg(-1)). Also, the composite electrochemical capacitor exhibits a stable cyclic life in the potential range of 0-1.0V. (c) 2006 Elsevier B.V. All rights reserved.