期刊
TETRAHEDRON
卷 63, 期 3, 页码 598-601出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2006.11.022
关键词
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Titanium(IV) complexes of bidentate trans-cyclohexane 1,2-diamine-based unsymmetrical chiral bis(sulfonamide) ligands were evaluated as catalysts for the asymmetric addition of diethylzinc to aldebydes. The reaction provided secondary alcohols in quantitative yields and very good enantioselectivity (up to 96% ee). (c) 2006 Elsevier Ltd. All rights reserved.
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