期刊
ORGANIC LETTERS
卷 9, 期 2, 页码 363-366出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol062885a
关键词
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资金
- NIGMS NIH HHS [GM69704, R15 GM069704, R15 GM069704-01] Funding Source: Medline
Two types of domino reactions from the same internal alkynes and hindered Grignard reagents based on carbopalladation, Pd-catalyzed cross-coupling reaction, and a C-H activation strategy are described. The realization of these domino reactions relied on the control of the use of the ligand and the reaction temperature. Our study provides efficient access to useful polysubstituted indenes and cis-substituted stilbenes and may offer a new means of development of tandem/domino reactions in a more efficient way.
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