期刊
JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY
卷 55, 期 2, 页码 414-420出版社
AMER CHEMICAL SOC
DOI: 10.1021/jf0617521
关键词
epicatechin; glycation; Maillard reaction; 3-deoxy-2-hexosulose; inhibit; carbonyl trapping
The influence of the polyphenolic compound epicatechin on Maillard chemistry was investigated under simulated roast conditions (10% moisture at 220 degrees C for 10 min). Quantitative gas chromatography (GC) analysis indicated that the addition of epicatechin to glucose or fructose/glycine model systems significantly reduced the generation of hydroxyacetone, 2-methylpyrazine, 2,3,5-trimethylpyrazine, furfural, 2-acetylfuran, 5-methylfurfural, 2(5H)-furanone, 2-acetylpyrrole, and furfuryl alcohol. These analytes were reported to be primarily generated from intact C-2, C-3, C-4, C-5, and C-6 sugar fragments based on gas chromatography/mass spectrometry quantitative isotopomeric analysis of a 1:1 C-13(6):C-12(6) hexose sugar/glycine model system. Liquid chromatography/mass spectrometry qualitative isotopomeric analysis of a 1:1 C-13(6):C-12(6) hexose sugar/glycine/epicatechin model systems confirmed epicatechin reacted with Maillard reactants in the model systems; two main reaction products were reported, epicatechin-C-5 and -C-6 sugar fragment adducts. In addition, LC/MS analysis of a model system consisting of only 3-deoxy-2-hexosulose and epicatechin identified 3-deoxy-2-hexosulose as a precursor of the epicatechin-C-5 and -C-6 sugar fragment adducts reaction products. These results imply that epicatechin quenched 3-deoxy-2-hexosulose (a key source C-6 to C-1 sugar fragments) and consequently inhibited Maillard product formation.
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